Search results for "water [Cherenkov counter]"
showing 10 items of 2170 documents
Evaluating the Utilization of Innovative Electrochemical Methodologies for the Real Wastewater Treatment
2021
Calibration of an airborne HO<sub><i>x</i></sub> instrument using the All Pressure Altitude-b…
2020
Abstract. Laser-induced fluorescence (LIF) is a widely used technique for both laboratory-based and ambient atmospheric chemistry measurements. However, LIF instruments require calibrations in order to translate instrument response into concentrations of chemical species. Calibration of LIF instruments measuring OH and HO2 ( HOx ) typically involves the photolysis of water vapor by 184.9 nm light, thereby producing quantitative amounts of OH and HO2 . For ground-based HOx instruments, this method of calibration is done at one pressure (typically ambient pressure) at the instrument inlet. However, airborne HOx instruments can experience varying cell pressures, internal residence times, tempe…
Ab initio determination of the ionization potentials of water clusters (H2O)n (n = 2-6).
2012
High-level quantum-chemical ab initio coupled-cluster and multiconfigurational perturbation methods have been used to compute the vertical and adiabatic ionization potentials of several water clusters: dimer, trimer, tetramer, pentamer, hexamer book, hexamer ring, hexamer cage, and hexamer prism. The present results establish reference values at a level not reported before for these systems, calibrating different computational strategies and helping to discard less reliable theoretical and experimental data. The systematic study with the increasing size of the water cluster allows obtaining some clues on the structure and reductive properties of liquid water.
Recognition of self-assembled water-nitrate cluster in a Co(III)-2,2′-bipyridine host: Synthesis, X-ray structure, DNA cleavage, molecular docking an…
2016
A mononuclear cobalt(III) complex [Co(bpy)2Cl2]NO3⋅2H2O (1) (bpy = 2,2′-bipyridine) has been synthesized and crystallographically characterized. Self-assembly of the lattice water molecules from rectangular tetrameric water cluster interacts with nitrate anion along the c-axis forming a six membered hexagonal water-nitrate cluster. It presents a new mode of association of water molecules with nitrate molecules which is not predicted theoretically or found experimentally. The molecule effectively cleaves bacterial genomic DNA and shows important cytotoxicity against human hepatocarcinoma cell (HepG2).
Modeling Rain Isotopic Composition under Orographic Control: A Landscape Approach for Hydrogeological Applications
2021
Oxygen isotopic composition is useful for individuating recharge areas of groundwater bodies by the comparison with those of local rainfalls. While on a global scale general relationships, such as the isotopic vertical gradient or continentality effects, efficiently describe spatial variations of the isotopic signature, hydrogeological applications need spatial models that are more focused on the effects of local topographic structures and/or subsoil geology. This work presents a case study in northeastern Sicily (Italy) characterized by complex geological and orographic structures, in which isotopic composition of rainfalls is governed by orographic effects and the varying initial composit…
Dimensionless Stage-Discharge Relationship for a Non-Linear Water Reservoir: Theory and Experiments
2020
In the field of hydrology, stage&ndash
Seasonal Analysis of Surface Soil Moisture Dry-Downs in a Land-Atmosphere Hotspot as Seen by LSM and Satellite Products
2018
The soil drying process is a challenging framework to assess climatic, hydrologic and ecosystem processes. This work develops a seasonal analysis of temporal e-folding decay ( $\tau$ ) of surface soil moisture dry-downs using ORCHIDEE land surface model and SMOS observations over South Eastern South America (SESA). Results show that the soil drying process depends on both location and season, and that the modeled drying velocity is faster than the observed one, even when modeled data is sampled at the same frequency as the observations. Differences between observed and modeled data have been found both in the analysis of the regional overall $\tau$ and in the spatial patterns of $\tau$ esti…
Budyko’s Based Method for Annual Runoff Characterization across Different Climatic Areas: an Application to United States
2018
Runoff data knowledge is of fundamental importance for a wide range of hydrological, ecological, and socioeconomic applications. The reconstruction of annual runoff is a fundamental task for several activities related to water resources management, especially for ungauged basins. At catchment scales, the Budyko's framework provides an extremely useful and, in some cases, accurate estimation of the long-term partitioning of precipitation into evapotranspiration and runoff as a function of the prevailing climatic conditions. Recently the same long-term partitioning rules have been successfully used to describe water partitioning also at the annual scale and calculate the annual runoff distrib…
2019
Abstract. This study uses the synergy of multi-resolution soil moisture (SM) satellite estimates from the Soil Moisture Ocean Salinity (SMOS) mission, a dense network of ground-based SM measurements, and a soil–vegetation–atmosphere transfer (SVAT) model, SURFEX (externalized surface), module ISBA (interactions between soil, biosphere and atmosphere), to examine the benefits of the SMOS level 4 (SMOS-L4) version 3.0, or “all weather” high-resolution soil moisture disaggregated product (SMOS-L43.0; ∼1 km). The added value compared to SMOS level 3 (SMOS-L3; ∼25 km) and SMOS level 2 (SMOS-L2; ∼15 km) is investigated. In situ SM observations over the Valencia anchor station (VAS; SMOS calibrati…
Intercomparison of Soil Moisture Retrieved from GNSS-R and from Passive L-Band Radiometry at the Valencia Anchor Station
2019
In this paper, the SOMOSTA (Soil Moisture Monitoring Station) experiment on the intercomparison of soil moisture monitoring from Global Navigation Satellite System Reflectometry (GNSS-R) signals and passive L-band microwave radiometer observations at the Valencia Anchor Station is introduced. The GNSS-R instrument has an up-looking antenna for receiving direct signals from satellites, and a dual-pol down-looking antenna for receiving LHCP (left-hand circular polarization) and RHCP (right-hand circular polarization) reflected signals from the soil surface. Data were collected from the three different antennas through the two channels of Oceanpal GNSS-R receiver and, in addition, calibration …